List sessions

select * from pg_stat_activity;

Kill a single session

select pg_terminate_backend(pid)
from   pg_stat_activity
where  pid = '1234';

Kill everyone else

SELECT pg_terminate_backend(pid)
FROM   pg_stat_activity
WHERE  pid <> pg_backend_pid() -- don't kill my own connection!
-- don't kill the connections to other databases
AND    datname = 'db-name';